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Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
1. Identification
GHS Product
Identifier
Company Name
Parchem Construction Supplies Pty Ltd (ABN 80 069 961 968) Telephone/Fax
Number
Emergency phone
number
Recommended use of Hardener component of abrasion resistant sprayable epoxy lining mortar
the chemical and
restrictions on use
Other Information
This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the workplace. Since Parchem Construction Supplies Pty Ltd cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available upon request.
www.parchem.com.au 2. Hazard Identification
GHS classification of Classified as Hazardous according to the Globally Harmonised System of
Classification and labelling of Chemicals (GHS) including Work, Health and substance/mixture
Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition)Acute Toxicity - Oral, Category 4Acute Toxicity - Inhalation, Category 4Acute Toxicity - Dermal, Category 5Skin Corrosion/irritation, Category 1 Serious eye damage/irritation, Category 1Skin Sensitiser, Category 1Hazardous to the Aquatic Environment - Long-Term Hazard, Category 3 Signal Word (s)
Hazard Statement (s)
H302 Harmful if swallowed. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H412 Harmful to aquatic life with long lasting effects.
Pictogram (s)
Precautionary
P102 Keep out of reach of children. P103 Read label before use. statement –
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. -This statement does not apply where this is the intended use. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary
P101 If medical advice is needed, have product container or label at hand. -This statement applies only where the substance is available to the general statement – Response public.
P310 Immediately call a POISON CENTER or doctor/physician. INGESTION. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomitingINHALATIONP304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. EYESP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. SKINP303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse.
Precautionary
statement – Storage
Precautionary
P501 Dispose of contents/container to an approved waste disposal plant statement – Disposal
3. Composition/information on ingredients
Ingredients
Proportion
4. First-aid measures
Inhalation
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Seek medical attention.
Ingestion
Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ensure contaminated clothing is washed before re-use or discard. Seek immediate medical attention.
Eye contact
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention.
First Aid Facilities
Eye wash, safety shower and normal washroom facilities.
Advice to Doctor
Other Information
For advice, contact a Poisons Information Centre (Phone eg Australia 131 126; New Zealand 0800 764 766) or a doctor (at once).
5. Fire-fighting measures
Suitable
Use carbon dioxide, dry chemical, foam or water mist.
extinguishing media
Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
Hazards from
Under fire conditions this product may emit toxic and/or irritating fumes including carbon monoxide, carbon dioxide and oxides of nitrogen.
Combustion
Products
Specific hazards
arising from the
chemical
Hazchem Code
Precautions in
Fire-fighters should wear full protective clothing and self contained breathing apparatus (SCBA) operated in positive pressure mode. Water spray connection with Fire
may be used to keep fire exposed containers cool.
6. Accidental release measures
Emergency
Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources of ignition and stop leak if safe Procedures
to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations.
7. Handling and storage
Precautions for Safe
Corrosive liquid. Attacks skin and eyes. May produce severe burns. Wear suitable protective clothing, gloves and eye/face protection when mixing and Handling
using. Use in designated areas with adequate ventilation. Avoid breathing in vapours, mist or fumes. Keep containers closed when not in use. Ensure a high level of personal hygiene is maintained when using this product, that is, always wash hands after handling, and before eating, drinking, smoking or using the toilet facilities. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous. Prevent the build up of mists or vapours in the work atmosphere. Keep containers sealed when not in use.
Conditions for safe
Corrosive and combustible liquid for storage and handling purposes. Keep tightly closed in a dry, cool, well-ventilated area, out of direct sunlight. storage, including
Provide a catch-tank in a bunded area. Avoid sparks, flames and other ignition any incompatabilities
sources. Store away from incompatible materials. Do NOT pressurise, cut, heat or weld containers as they may contain hazardous residues. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design of the store-room reference should be made to Australian Standard AS1940 - The storage and handling of flammable and combustible liquids and AS 3780-2008 The storage and handling of corrosive substances. Reference should also be made to all Local, State and Federal regulations.
Storage Regulations
Classified as a Class C1 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS1940.
8. Exposure controls/personal protection
Occupational
No exposure standards have been established for this material by Safework, Australia. However, as with all chemicals, exposure should be kept to the exposure limit values
Biological Limit
Values
Appropriate
Provide sufficient ventilation to keep airborne levels below the exposure limits. Where vapours or mists are generated, particularly in enclosed areas, engineering controls
and natural ventilation is inadequate, a local exhaust ventilation system is required.
Respiratory
If engineering controls are not effective in controlling airborne exposure then respiratory protective equipment should be used suitable for protecting Protection
against airborne contaminants. Final choice of appropriate breathing Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
protection is dependent upon actual airborne concentrations and the type of breathing protection required will vary according to individual circumstances. Expert advice may be required to make this decision. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices.
Eye Protection
Safety glasses with side shields, goggles or full-face shield as appropriate recommended. Final choice of appropriate eye/face protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Hand Protection
Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.
Body Protection
Suitable workwear should be worn to protect personal clothing, eg cotton overalls buttoned at neck and wrist. When large quantities are handled the use of plastic aprons and rubber boots is recommended.
9. Physical and chemical properties
Appearance
Melting Point
Boiling Point
Solubility in Water
Specific Gravity
Vapour Pressure
Vapour Density
(Air=1)
Evaporation Rate
Odour Threshold
Viscosity
Partition Coefficient: Not available
n-octanol/water
Flash Point
Flammability
Auto-Ignition
Temperature
Flammable Limits -
Lower
Flammable Limits -
10. Stability and reactivity
Chemical Stability
Conditions to Avoid
Heat, flames and other ignition sources.
Incompatible
Materials
Hazardous
Thermal decomposition may result in the release of toxic and/or irritating fumes and gases including carbon dioxide, carbon monoxide, ammonia and oxides Decomposition
Products
Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
Hazardous
Polymerization
11. Toxicological Information
Toxicology
No toxicity data available for this material.
Information
Inhalation
Harmful by inhalation. Inhalation of mists or vapours will result in respiratory irritation and possible harmful corrosive effects including lesions of the nasal septum, pulmonary edema, pneumonitis and emphysema.
Ingestion
Harmful if swallowed. Ingestion of this product may cause nausea, vomiting, abdominal pain and chemical burns to the mouth, throat and stomach.
Causes burns. Corrosive to the skin. Skin contact can cause redness, itching, irritation, severe pain and chemical burns with resultant tissue destruction. Skin contact will cause redness, itching, irritation, severe pain and chemical burns with resultant tissue destruction. May be harmful in contact with skin. Prolonged or repeated skin contact may cause defatting leading to skin burns and skin sensitisation.
Eye contact can cause stinging, blurring, tearing, severe pain and possible permanent corneal damage.
Reproductive
Not considered to be toxic to reproduction.
Toxicity
Carcinogenicity
Product contains crystalline silica. Crystalline Silica (respirable size <= 7 µm) has been classified by the International Agency for Research on Cancer (IARC) as Carcinogenic to Humans (Group 1).
Skin Sensitisation
May cause an allergic skin reaction.
Aspiration Hazard
Not expected to be an aspiration hazard.
STOT-single
Not expected to cause damage to organs.
exposure
STOT-repeated
Not expected to cause damage to organs.
exposure
Germ cell
Not considered to be a mutagenic hazard.
mutagenicity
Respiratory
Not expected to be a respiratory sensitiser sensitisation
Other Information
This product contains crystalline silica (quartz). No exposure to free respirable crystalline silica is anticipated during normal use of this product as silica is bound in the liquid/paste. It should be noted, however, that respirable crystalline silica has been listed as a Group 1 human carcinogen by the IARC. Inhalation of respirable silica may cause cancer, silicosis or other serious delayed lung injury. Grinding or machining of coated materials may release silica. Use approved dust respirator when grinding, sanding or machining the dried items.
12. Ecological information
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Persistence and
degradability
Mobility
Bioaccumulative
Potential
Environmental
Prevent this material entering waterways, drains and sewers.
Protection
13. Disposal considerations
Disposal
The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations.
Considerations
14. Transport information
Transport
Road and Rail Transport:This material is classified as a Class 8 (Corrosive Substances) Dangerous Information
Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition).
Class 8 Dangerous Goods are incompatible in a placard load with any of the following:- Class 1, Explosives- Division 4.3, Dangerous When Wet Substances- Division 5.1, Oxidising Agents- Division 5.2, Organic Peroxides- Class 6, Toxic or Infectious Substances, if the Class 6 dangerous goods are cyanides and the Class 8 dangerous goods are acids - Class 7, Radioactive Substancesand are incompatible with food and food packaging in any quantity.
Strong acids must not be loaded in the same freight container or on the same vehicle with strong alkalis. Packing Group I and II acids and alkalis should be considered as strong.
Marine Transport (IMO/IMDG):Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.
UN No.: 2735Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.(CONTAINS ISOPHORONEDIAMINE)Class: 8Packaging Group: IIIEMS No.: F-A, S-BAir Transport (ICAO/IATA):Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.
UN No: 2735Proper Shipping Name: Amines, liquid, corrosive, n.o.s.(Contains Isophoronediamine)Class: 8Packing Group: IIILabel: CorrosivePacking Instruction: 852 (For passenger and cargo aircraft)Packing Instruction: 856 (For cargo aircraft only)Special provisions: A3, A803 U.N. Number
UN proper shipping
AMINES, LIQUID, CORROSIVE, N.O.S. - (CONTAINS ISOPHORONE DIAMINE) name
Transport hazard
class(es)
Hazchem Code
Packing Group
EPG Number
IERG Number
IMDG Marine
pollutant
15. Regulatory information
Regulatory
Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Information
Safety regulations, AustraliaClassified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Poisons Schedule
16. Other Information
Safety Data Sheet
Product Name F
:OSROC NITOCOTE EP500 HARDENER
Date of preparation
or last revision of
SDS
Contact Person/Point Technical Support: 1800 812 864
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Source: http://www.parchem.com.au/public/pdfs/data-sheets/Fosroc-Nitocote-EP500-Hardener-SDS.pdf