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MATERIAL SAFETY DATA SHEET 03200
Chemical Product and Contact Information
Product Name: LECOSET 7000 Part Numbers:

Powder 813-083
LECO Corporation
3000 Lakeview
St. Joseph, Michigan 49085
813-004 813-005
Information:
269-983-5531
813-005-HAZ 813-056
Chemtrec:
800-424-9300
813-056-HAZ 813-056-010
(Chemtrec Int'l: 703-527-3887)
813-089 813-089-HAZ
Composition/Information on Ingredients
Silicate filler preparation with organic peroxide. 3. Hazard
Identification
EMERGENCY OVERVIEW
No unusual spill or fire hazard; minor irritant health hazard. Odorless whitish-grey powder.
Potential Health Effects

SKIN: Can be irritating; possible abrasion. INHALATION: Dust can be irritating to mucous membranes. MEDICAL CONDITIONS AGGRAVATED: Not available. CHRONIC OVEREXPOSURE: Progressive inhalation symptoms include silicosis and histologic fibrosis of the lungs. Repeated inhalation of respirable free silica dust may cause delayed lung disease (silicosis). CARCINOGENICITY: IARC labels crystalline silica as a 2A (probable human) carcinogen. P/N: 813-083
MATERIAL SAFETY DATA SHEET 03200
First Aid Measures
EYES: Flush eyes with water for 15 minutes. SKIN: Wash exposed area with soap and water. Wash contaminated clothing. Fire Fighting Measures
AUTO-IGNITION TEMPERATURE: Not applicable. HAZARDOUS COMBUSTION PRODUCTS: Not available. FIREFIGHTING INSTRUCTIONS: Not available. Accidental Release Measures
SMALL/LARGE SPILL: Take up mechanically. Handling and Storage
HANDLING: Avoid formation of dust; do not breathe dust. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Provide sufficient mechanical (General and/or Local Exhaust) ventilation to maintain exposure below TLVs or PELs. RESPIRATORY PROTECTION: Recommended if TLVs or PELs are exceeded. Use SKIN AND HAND PROTECTION: Wear gloves if necessary. EYE AND FACE PROTECTION: Safety glasses with side shields. OTHER PROTECTIVE EQUIPMENT: Not available. P/N: 813-083
MATERIAL SAFETY DATA SHEET 03200
Physical and Chemical Properties
VAPOR DENSITY (air = 1): 2.2 - 2.5 g/cm3 @ 68° F. (20° C.) EVAPORATION RATE (Butyl Acetate = 1): Not available. Stability and Reactivity
INCOMPATIBILITY: Hydrofluoric acid and powerful oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Degradation of the peroxide occurs at Toxicological Information
Ecological Information
Disposal Consideration
Observe all federal, state and local laws. Because of the peroxide content, the material must not get Transportation Information
P/N: 813-083
MATERIAL SAFETY DATA SHEET 03200
Regulatory Information
Section 302 Extremely Hazardous Substances: Other Information
Hazard Index: (0 - 4, 4 = Extreme)
Health: 1
Reactivity: 0
Jason Whitt
Information herein is given in good faith as authoritative and valid; however, no warranty, expressed
or implied can be made.
P/N: 813-083
MATERIAL SAFETY DATA SHEET 03210
Chemical Product and Contact Information
LECOSET 7000
Part Numbers:
Liquid II
813-084 813-084-HAZ
813-084-010
813-087-HAZ
813-087-010
813-109-HAZ
813-111-HAZ
LECO Corporation
Kit: 813-004 813-005
3000 Lakeview
813-005-HAZ 813-056
St. Joseph, Michigan 49085
813-056-HAZ 813-056-010
Information:
269-983-5531
813-089 813-089-HAZ
Chemtrec:
800-424-9300
813-108-HAZ
(Chemtrec
Int'l: 703-527-3887)
Composition/Information on Ingredients
Dipropan-2-ol (Most data in this sheet is for Methyl Methacrylate.) 3. Hazard
Identification
EMERGENCY OVERVIEW
Serious fire hazard, minor spill hazard; moderate general health risk. Light green liquid with characteristic odor. Potential Health Effects

SKIN: Harmful by contact. May cause sensitization MEDICAL CONDITIONS AGGRAVATED: Not available. CHRONIC OVEREXPOSURE: Repeated or prolonged contact may cause allergic skin rash, itching, swelling. ACUTE OVEREXPOSURE: Inhalation overexposure may cause eye, nose and throat irritation. May cause central nervous system effects such as dizziness, headache, nausea, and loss of consciousness. P/N: 813-084
MATERIAL SAFETY DATA SHEET 03210
CARCINOGENICITY: Styrene is listed by IARC as a Group 2B carcinogen. First Aid Measures
EYES: Rinse opened eye with plenty of running water for at least 15 minutes; seek medical advice. SKIN: Wash skin with plenty of soap and water. INHALATION: Fresh air, for safety seek medical advice. In case of unconsciousness, place and INGESTION: Induce vomiting, seek medical advice immediately. Symptoms of poisoning may develop many hours later, therefore medical supervision for at least 48 hours after an accident. Fire Fighting Measures
AUTO-IGNITION TEMPERATURE: Not applicable. HAZARDOUS COMBUSTION PRODUCTS: Formation of toxic gases. EXTINGUISHING MEDIA: Carbon dioxide, water spray jet, foam, powder type fire extinguisher. FIREFIGHTING INSTRUCTIONS: Keep away from sources of ignition, take precautionary measures against static discharges. Cool containers in danger of catching fire. Highly flammable. Keep away from sources of ignition - no smoking. Accidental Release Measures
SMALL/LARGE SPILL: Wear protective equipment. Keep unprotected people away. Take up carefully with absorbent material (diatomaceous earth, sand, universal binding agent), dispose of according to regulations. Handling and Storage
HANDLING: Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. After contact with skin, wash immediately with plenty of soap and water. Do not empty into drains. Fill container only 80%. Keep away from food. STORAGE: Keep container closed in a well-ventilated place. Store in a cool area (not above room Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Provide efficient local exhaust. RESPIRATORY PROTECTION: NIOSH/OSHA approved respiratory protection. SKIN AND HAND PROTECTION: Appropriate gloves. OTHER PROTECTIVE EQUIPMENT: Usual industrial hygiene; keep work clothes separate. Immediately take off all P/N: 813-084
MATERIAL SAFETY DATA SHEET 03210
Physical and Chemical Properties
VAPOR PRESSURE (mm): 40 mbar @ 68° F. (20° C.) SOLUBILITY IN WATER: Not miscible or difficult to mix PERCENT VOLATILES: 49.5 %. SOLIDS CONTENT: 40.9% EVAPORATION RATE (Butyl Acetate = 1): Not available. Stability and Reactivity
HAZARDOUS DECOMPOSITION PRODUCTS: None with correct use and handling. HAZARDOUS POLYMERIZATION: If storage time and/or temperature is considerably exceeded, product may polymerize under generation of heat. Toxicological Information
N, N-dimethyl-p-toluidine LD/LC50 oral rat: 50mg/kg. Irritant for skin and mucous membranes. Sensitization possible by skin contact Ecological Information
Do not allow product to reach ground water or water system. Disposal Consideration
Dispose of according to federal and local regulations. Dispose of empty containers only after cleaning. Do not empty into waters or drains. Transportation Information
U.S.A. DOT: Methyl Methacrylate Monomer, Stabilized, 3(Flammable Liquid) UN1247, PGII, (Flash Point 55°F/13°C IMDG Page No. 50. P/N: 813-084
MATERIAL SAFETY DATA SHEET 03210
Regulatory Information
CERCLA REPORTABLE QUANTITY: Styrene, 1000 lbs. Section 302 Extremely Hazardous Substances: Other Information
Hazard Index: (0 – 4), 4 = Extreme
Health: 2
Flammability: 3
Reactivity: 2
Jason Whitt
Information herein is given in good faith as authoritative and valid; however, no warranty, expressed
or implied can be made.
P/N: 813-084
MATERIAL SAFETY DATA SHEET 03220
Chemical Product and Contact Information
Product Name: LECOSET 7000 Part Numbers:

I 813-085 813-085-HAZ
813-085-010
813-088-HAZ 813-088-010
813-110-HAZ
813-112-HAZ
LECO Corporation
Kit: 813-004 813-005
Lakeview
813-005-HAZ 813-056
St. Joseph, Michigan 49085
813-056-HAZ 813-056-010
Information:
269-983-5531
813-089 813-089-HAZ
Chemtrec:
800-424-9300
813-108-HAZ
(Chemtrec
Int'l: 703-527-3887)
Composition/Information on Ingredients
3. Hazard
Identification
EMERGENCY OVERVIEW
Serious fire hazard (flammable) and minor spill hazard; minor skin/inhalation health risk. Light yellow liquid with characteristic odor. Potential Health Effects

SKIN: May cause skin sensitization by contact. MEDICAL CONDITIONS AGGRAVATED: Not available. CHRONIC OVEREXPOSURE: Repeated or prolonged contact may cause allergic skin rash, CARCINOGENICITY: Styrene is listed by IARC as a Group 2B carcinogen. P/N: 813-085
MATERIAL SAFETY DATA SHEET 03220
First Aid Measures
EYES: Rinse opened eye with plenty of running water for at least 15 minutes; seek medical advice. SKIN: Wash skin with plenty of soap and water. INHALATION: Remove to fresh air. Seek medical aid if necessary. INGESTION: Induce vomiting, seek medical advice immediately, symptoms of poisoning may develop many hours later, therefore medical supervision for at least 48 hours after an accident. Fire Fighting Measures
AUTO-IGNITION TEMPERATURE: Not applicable. HAZARDOUS COMBUSTION PRODUCTS: None with correct use and handling. EXTINGUISHING MEDIA: Carbon dioxide, water spray jet, foam, powder type fire extinguisher. FIREFIGHTING INSTRUCTIONS: Keep away from sources of ignition, take precautionary measures against static discharges. Cool containers in danger of catching fire. Flammable. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharge. Accidental Release Measures
SMALL/LARGE SPILL: Take up carefully with absorbent material (diatomaceous earth, sand, universal binding agent). Wear protective clothing, keep unprotected people out. Dispose according to regulations. Handling and Storage
HANDLING: Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. Do not empty into drains. Take precautionary measures against static discharges. Keep away from sources of ignition. Protect from light. Good ventilation of the room and workplace is recommended. Avoid formation of aerosols. STORAGE: Keep container tightly closed in a cool, well-ventilated place. Fill container only 80%, Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Provide efficient local exhaust. RESPIRATORY PROTECTION: NIOSH/OSHA approved respirator. SKIN AND HAND PROTECTION: Appropriate gloves. OTHER PROTECTIVE EQUIPMENT: Usual industrial hygiene; keep work clothes separate. Take off immediately all contaminated clothing. P/N: 813-085
MATERIAL SAFETY DATA SHEET 03220
Physical and Chemical Properties
VAPOR PRESSURE (mm): 47.0 mbar at 20  C. SOLUBILITY IN WATER: Not miscible or difficult to mix PERCENT VOLATILES: 15.0%. SOLIDS CONTENT: 55.0 % EVAPORATION RATE (Butyl Acetate = 1): Not available. Stability and Reactivity
INCOMPATIBILITY: None with correct use and handling. HAZARDOUS DECOMPOSITION PRODUCTS: None with correct use and handling. HAZARDOUS POLYMERIZATION: If storage time and/or temperature is considerably exceeded, product may polymerize under generation of heat. Toxicological Information
Methyl methacrylate is acutely only slightly toxic: Long-term inhalation tests with rats and hamsters gave no indication of chronic toxicity. Styrene: Oral Rat LD50: 5000 mg/kg, Inhalation Rat LD50: 24 mg/l/4 hr Ecological Information
Hazardous to water, Class 2 (styrene); do not empty into waters or drains. Hazardous to drinking water even on leakage of small quantities into the ground. Disposal Consideration
Dispose of according to federal and local regulations. Dispose of empty containers only after Transportation Information
U.S.A. DOT: Methyl Methacrylate Monomer, Stabilized, 3(Flammable Liquid) UN1247, PGII, (Flash Point 55°F/13°C IMDG Page No. 50. P/N: 813-085
MATERIAL SAFETY DATA SHEET 03220
Regulatory Information
CERCLA REPORTABLE QUANTITY: Styrene, 1000 lbs. Section 302 Extremely Hazardous Substances: Other Information
Hazard Index:
(0-4), 4 = extreme
Health: 2
Flammability: 3
Reactivity: 2
Jason Whitt
Information herein is given in good faith as authoritative and valid; however, no warranty, expressed
or implied can be made.
P/N: 813-085

Source: http://app.leco.cz/resources/031-040/03200-10-20.pdf